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饶伟浩

时间:2018-09-18 17:22:11来源:本站编辑 作者:本站编辑阅读:

饶伟浩,博士,硕士生导师。于2008、2011年分别获得河南师范大学学士、硕士学位,于2016年获得浙江大学理学博士学位。2016年4月起任职于信阳师范学院304永利集团官网入口。主要从事过渡金属催化的碳氢键活化、烯烃双官能团化反应、自由基化学的研究,并利用所发展的方法学高效构建各类杂环骨架以及糖苷化合物。欢迎对过渡金属催化的碳氢键活化、烯烃双官能团化反应、自由基化学、各类杂环骨架和糖苷化合物的合成感兴趣的本科生和研究生加入本课题组。

联系方式

联系地址:信阳市南湖路237号化学实验楼519 办公室

实验室:化学实验楼510

Email:rwhxynu@163.com;电话:18237610525

研究领域与兴趣:

1. 过渡金属催化的碳氢键活化;

2. 烯烃双官能团化反应;

3. 自由基化学。

主讲课程:

本科生:《有机合成化学》、《有机化学实验》

研究生:《有机合成化学》、《实验室安全与环境》、《实验数据与处理》

在研项目:

1.国家自然科学基金青年基金项目1项(主持);

2.河南省自然科学基金面上项目1项(主持);

3. 国家自然科学基金面上项目1项(参与)。

代表性论文:

(1) Wei-Hao Rao*, Li-Li Jiang, Jin-Xiao Zhao, Xin Jiang, Guo-Dong Zou, Yu-Qiang Zhou, and Lin Tang. Selective O-Cyclization of N-Methoxy Aryl Amides with CH2Br2 or 1,2-DCE via Palladium-Catalyzed C–H Activation. Org. Lett., 2018, DOI: 10.1021/acs.orglett.8b02678.

(2) Wei-Hao Rao, Bing-Feng Shi*, Recent Advances in Copper‐Mediated Chelation-Assisted Functionalization of Unactivated C–H Bonds, Org. Chem. Front., 2016, 3: 1028-1047.

Before XYNU

(3) Wei-Hao Rao, Xue-Song Yin,Bing-Feng Shi*, Catalyst-Controlled Amino-versus Oxy-Acetoxylation of Urea-Tethered Alkenes: Efficient Synthesis of Cyclic Ureas and Isoureas, Org. Lett., 2015, 17(15): 3758-3761.

(4) Wei-Hao Rao, Bei-Bei Zhan, Kai Chen, Peng-Xiang Ling, Zhuo-Zhuo Zhang, Bing-Feng Shi*, Pd(II)-Catalyzed Direct Sulfonylation of Unactivated C(sp3)–H Bonds with Sodium Sulfinates, Org. Lett., 2015, 17(14): 3552-3555.

(5) Wei-Hao Rao,Bing-Feng Shi*,Copper(II)-Catalyzed Direct Sulfonylation of C(sp2)–H Bonds with Sodium Sulfinates, Org. Lett., 2015,17(11):2784-2787.

(6) Jing-Wen Xu, Zhuo-Zhuo Zhang, Wei-Hao Rao, Bing-Feng Shi*, Site-Selective Alkenylation of δ-C(sp3)−H bonds with Alkynes via a Six-Membered Palladacycle, J. Am. Chem. Soc., 2016, 138(34): 10750-10753.

(7) Qi Zhang, Kai Chen, Weihao Rao, Yuejun Zhang, Fa-Jie Chen, Bing-Feng Shi*, Stereoselective Synthesis of Chiral α-Amino-β-Lactams through Palladium(II)-CatalyzedSequential Arylation/Amidation of C(sp3)-H Bonds, Angew. Chem. Int. Ed., 2013, 52(51): 13588-13592.

(8) Gui-Rong Qu, Lei Liang, Hong-Ying Niu, Wei-Hao Rao, Hai-Ming Guo*, John S. Fossey*, Copper-Catalyzed Synthesis of Purine-Fused Polycyclics, Org. Lett., 2012, 14(17): 4494-4497.

(9) Hai-Ming Guo*, Li-Li Jiang, Hong-Ying Niu, Wei-Hao Rao, Lei Liang, Run-Ze Mao, De-Yang Li, Gui-Rong Qu*, Pd(II)-Catalyzed Ortho Arylation of 6-Arylpurines with Aryl Iodides via Purine-Directed C–H Activation: A New Strategy for Modification of 6-Arylpurine Derivatives, Org. Lett., 2011, 13(8): 2008-2011.

(10) Hai-Ming Guo*, Wei-Hao Rao, Hong-Ying Niu, Li-Li Jiang, Lei Liang, Yang Zhang, Gui-Rong Qu*, Chelation-assisted palladium-catalyzed high regioselective heck diarylation reaction of 9-allyl-9H-purine: synthesis of 9-(3,3-diaryl-allyl)-9H-purines, RSC Adv., 2011, 1(6): 961-963.

(11) Hai-Ming Guo*, Wei-Hao Rao, Hong-Ying Niu, Li-Li Jiang, Ge Meng, Jia-Jia Jin, Xi-Ning Yang, Gui-Rong Qu*, Palladium-Catalyzed C–H Bond Functionalization of C6-Arylpurines,Chem. Commun., 2011, 47:5608-5610